The area of risk in sodium hydroxide is shown on the iso corrosion diagram by the area bounded by a green line. Caustic embrittlement is also known as stress corrosion cracking. The nace caustic soda service graph nace, 1985 indicates a safe region where stress relief of carbon steels is not specified below certain operating. This phenomenon mostly occurs in boilers where caustic soda naoh has been added in. Mild steels steels with low carbon and low alloy content and stainless steels will. The use of corrosion inhibitors, soda ash, caustic, filters, or reclaimers has no indicated effect on cracking tendencies. The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was. Caustic stress corrosion cracking is a form of degradation that is caused when a. Citeseerx document details isaac councill, lee giles, pradeep teregowda. Caustic soda naoh was added in small amounts to boiler water to prevent scaling but the presence of caustics alkalis, usually concentrated in crevices around rivet heads and at hot spots, combined with the considerable fabrication stresses around rivet holes to caused cracking of. In alkaline solutions, the concentration of hydrogen ions is usually low and the corrosion rate in chemical media usually decreases with the increase of ph value. This pretreatment is the removing of the remaining grease from the object. Nace sp0403 avoiding caustic stress corrosion cracking.
Localized corrosion, mostly pitting, took place when the caustic soda solutions became dilute. Stress corrosion cracking of carbon steel in caustic. Caustic stress corrosion cracking inspectioneering. Effect of carbon on stress corrosion cracking and anodic. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Corrosion of carbon steel in hot naoh solutions under heat.
Percentage elongation and reduction in crosssectional area were used to. The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was studied by fracturing this material on a tensometer after every seven days of immersion in these media. Crack propagation can increase dramatically with temperature and can grow through the wall in a matter of hours during temperature excursions especially in conditions that promote caustic. Carbon cracking caused intergranular scc in both media due to retained internal stresses in the steel while hydrogen cracking also occurred in caustic soda. This standard establishes recommended practices to avoid caustic scc of cs refinery equipment and piping. Various nickel alloys also have been widely used in sodium hydroxide production and in many other. The term caustic embrittlement is a misnomer be cause the phenomenon is simply scc of steel in the alkaline solution. Stress corrosion cracking of carbon steel in amine systems. Caustic stress corrosion cracking of mild steel springerlink. Nicrmo alloys the nicrmo alloys are particularly resistant to the insidious and unpredictable forms of corrosion caused by chlorides. Specialized corrosion doehdbk1015193 corrosion ch02 rev.
Some general guidance is provided in appendices a and b. Caustic stress corrosion cracking caustic embrittlement. It becomes increasingly more corrosive with increasing temperature and concentration. As a general rule, the resistance to caustic solutions increases with. Stress corrosion cracking scc or environmentally induced cracking could occur at any. The corrosion rate obtained in the boiling solution was larger than that in the hydrogensaturated solution of the same concentration and temperature in all. Carbon steel was fairly passive in naoh solutions of 0. During the early 1990s, several incidents of caustic stress corrosion cracking of carbon steel were encountered within company gas plants and refineries mcintyre 1994. Corrosion resistance of nici caustic soda, and selection is based upon such factors as concentration.
I have to buy a new recipient for pretreatment of nickel plating as a step on chrome plating process. Caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking which can occur at temperatures as low as 60 degc. Caustic cracking definition caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or. Caustic soda is used in several refinery processes, for example in crude distillation units for chloride corrosion control and in some mercaptan removal units. The lower limit for cracking appears to be in the range of a few percent by weight of caustic as naoh. Stress corrosion cracking of carbon steel in caustic aluminate. Because the total test period for start up is relatively short, penetration will not occur. Caustic embrittlement or caustic cracking occurs when the alloy material cracks under the action of tensile stress and corrosion medium in alkaline solution.
This mechanism has been extensively studied in stress corrosion cracking of alpha brass in ammoniacal environment and also proposed for caustic cracking of boiler steel. Stress corrosion cracking susceptibility of medium carbon steel in. The corrosion behavior of carbon steel, austenitic stainless steels, nibase alloys, and nickel in hot, concentrated caustic soda solutions at the active potential range was investigated. Stainless steels are more resistant to general corrosion compared with carbon steel.
There is caustic stress corrosion cracking when carbon steel is exposed to concentrated caustic solution. Carbon and lowalloy steels, austenitic stainless steels, and some nickel alloys may suffer either stresscorrosion cracking or general corrosion in hot, concentrated caustic solutions. This standard incorporates the findings of that survey as they apply to refinery applications. Usability of cs in caustic soda service to prevent scc. Corrosion by caustic sodium or potassium hydroxide at all concentrations is easily handled at room temperature with a variety of metals and alloys, including carbon steels. The nace curve correlating concentration of caustic and temperature is not being followed now a days by process designers. Attack of the most stressed areas of tubes welds and adjacent areas, with highly concentrated caustic soda, results in catastrophic sudden failure. As water evaporates in the boiler, the concentration of sodium carbonate increases in the boiler. Stress corrosion cracking caustic embrittlement of super.
Caustic embrittlement is the phenomena in which the material of a boiler becomes brittle due to the accumulation of caustic soda. Residual sodium carbonate, which is used for the softening process, undergoes hydrolysis, forming sodium hydroxide at high pressures and temperatures. The most common material of construction is carbon steel but its application is. Api 571 recommends the use of carbon steel materials with caustic soda naoh solution according to the concentration and temperature. Avoiding stress corrosion cracking of carbon low alloy and. Hightemperature electrochemical tests have resulted in the stress corrosion cracking of inconel600 and incoloy800 registered trademarks, international nickel company, and type 304 stainless steel in caustic solutions. Stress corrosion cracking of carbon steel in caustic aluminate solutions of the. However stress corrosion cracking, or caustic embrittlement as it was referred to in the past, can be a problem. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Results show that stress corrosion cracking of these alloys can be prevented or accelerated by varying their.
The useful safe limit of carbon steel is approximately 150 o f65 o c, both with regard to caustic stress corrosion cracking cscc and corrosion. Caustic embrittlement focuses on the stressed parts of the boiler, including cracks, bends, rivets and joints. Pdf caustic soda is used in several refinery processes, for example in. Carbon cracking caused intergranular scc in both media due to retained internal stresses in the steel while hydrogen cracking also occurred in caustic soda medium, hence mcs is more susceptible to scc in caustic soda medium than potash solution. Other higher nickel stainless alloys like alloy 20, 800 and 825 also resist caustic corrosion and caustic cracking better than the 300 series stainless steels. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Corrosion resistance of nickel alloys in caustic solutions. Caustic stress corrosion cracking of inconel600, incoloy. Caustic soda naoh was added in small amounts to boiler water to prevent scaling but the presence of caustics alkalis, usually concentrated in crevices around rivet heads and at hot spots, combined with the considerable fabrication stresses around rivet holes to caused cracking of the steel boiler shells and tube plates.
Sp04032015, avoiding caustic stress corrosion cracking. Published corrosion rates for steel in pure caustic at the elevated temperatures indicate losses 1. In carbon steel, cracking can be trasngranular along grain boundries as a network of very fine oxide filled cracks. Stress corrosion cracking scc of carbon steel in hot alkaline solutions was first observed in riveted steel boiler plates, and now it can be a problem in alumina producing plants which use hot caustic aluminate solutions,, in the pulp and paper industry which use hot naoh and na 2 s solutions, or in low alloy steel turbines due to the. Stress corrosion cracking behavior of nickel base alloys.
In 300 series ss cracking is typically transgranular through grains and very difficult to distinguish between chloride stress corrosion cracking. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. If the carbon steel tank had been postweld heat treated, there is no need to do any internal coating. Cracking occurs in all types of equipment and piping operating at all common temperatures. Industrial experience on the caustic cracking of stainless.
Sodium hydroxide these corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air the corrosion rate can be quite different if the solution is free from oxygen. The stress corrosion cracking scc behavior of cold worked mild steel in hot, aqueous, 33 pct naoh solutions was studied with prefatigue cracked double ca. Chromium induces passivation in oxidizing acids, as it does in the stainless steels. Pdf a case study on caustic corrosion in refinery piping. Carbon steel in caustic service corrosion engineering. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. So, lack of pwht will increase susceptibility, mostly from residual tensile stresses, and not just hardness. The main effect of caustic is stress corrosion cracking of carbon steel if not postweld heat treated. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel equipment. Standard recommended practice avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping. Cracking has been reported in all typical refinery streams containing hsub 2s, cosub 2, or a combination of the two. A discussion started in 1998 but continuing through 2018.
Failure of carbon steel piping by caustic stress corrosion cracking embrittlement and caustic gouging has been a recurring problem, several repairs attempts were made without success using patch. This phenomenon mostly occurs in boilers where caustic soda naoh. Caustic scc is driven by tensile stress, susceptible material and concentration of caustic. The intersection of the naohho boiling point curve with regions of caustic scc are. The model is based on the idea of a straininduced rupture of the protective film, and so plastic strains play a main role in failure processes. Caustic soda can be handled in cast iron or steel equipment at low temperatures. One of the materials most resistant to a variety of caustic solutions, as well as to molten caustic, is commercially pure nickel. The results obtained showed that mcs is susceptible to scc in both caustic soda and potash media. These alloys can be candidates for service in caustic exposure when corrosion from cooling waters is a concern. However, concern exists because the rust particles will probably circulate and precipitate throughout the system.
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